Gas Pressure and Volume (pV = constant)

✏️ Paper first! Work out every question on paper before you tap Show solution. Write down every step – the equation, the numbers with units, the rearranging and the answer with its unit. In the exam, if your final answer is wrong you can still get marks for correct working, but only if the examiner can see it.

Course: Separate Physics only  |  Tier: Foundation + Higher  |  Equation sheet: given in the exam

The equation

pressure × volume = constant (for a fixed mass of gas at constant temperature)    p V = constant, so p₁V₁ = p₂V₂

QuantitySymbolUnit
pressureppascals (Pa)
volumeVcubic metres (m³)

Rearranged: p₂ = p₁V₁ ÷ V₂  |  V₂ = p₁V₁ ÷ p₂  |  Tip: as long as both pressures use the same unit and both volumes use the same unit, you can keep kPa, cm³ or litres.

Use FIFA for every answer

  • F – Formula: write p₁V₁ = p₂V₂.
  • I – Insert: put in the numbers (matching units on both sides).
  • F – Fix: rearrange to make the unknown the subject.
  • A – Answer: calculate and always give the unit.

Foundation: aim for Q1–8.   Higher: aim for Q4–10. Every question needs rearranging.


Questions

Q1 (F) A gas at 100 kPa has a volume of 2.0 m³. It is slowly squashed to 1.0 m³ at constant temperature. Calculate the new pressure.

Show solution

F: p₁V₁ = p₂V₂
I: 100 × 2.0 = p₂ × 1.0
F: p₂ = 200 ÷ 1.0
A: 200 kPa

Q2 (F) A bicycle pump holds 120 cm³ of air at 100 000 Pa. The air is squashed until its pressure is 300 000 Pa. Calculate its new volume.

Show solution

F: p₁V₁ = p₂V₂
I: 100 000 × 120 = 300 000 × V₂
F: V₂ = 12 000 000 ÷ 300 000
A: 40 cm³

Q3 (F) A sealed syringe holds 50 cm³ of air at 100 kPa. The plunger is pulled out until the volume is 125 cm³. Calculate the new pressure.

Show solution

F: p₁V₁ = p₂V₂
I: 100 × 50 = p₂ × 125
F: p₂ = 5000 ÷ 125
A: 40 kPa

Q4 (F) A scuba tank holds 0.012 m³ of air at 20 000 kPa. What volume would the air take up at 100 kPa? Give your answer in litres.

Show solution

F: p₁V₁ = p₂V₂
I: 20 000 × 0.012 = 100 × V₂
F: V₂ = 240 ÷ 100 = 2.4 m³
A: 2.4 × 1000 = 2400 litres

Q5 (F) A sealed bag of crisps holds 500 ml of air at 100 kPa. It is taken up a mountain where the pressure is 80 kPa. Calculate the new volume of air.

Show solution

F: p₁V₁ = p₂V₂
I: 100 × 500 = 80 × V₂
F: V₂ = 50 000 ÷ 80
A: 625 ml

Q6 (F/H) A weather balloon contains 5.0 m³ of helium at 100 kPa. High in the atmosphere it expands to 25 m³. Calculate the pressure there (assume constant temperature).

Show solution

F: p₁V₁ = p₂V₂
I: 100 × 5.0 = p₂ × 25
F: p₂ = 500 ÷ 25
A: 20 kPa

Q7 (F/H) A 2.0 cm³ air bubble at the bottom of a lake is at 200 kPa. It rises to the surface where the pressure is 100 kPa. Calculate its volume at the surface.

Show solution

F: p₁V₁ = p₂V₂
I: 200 × 2.0 = 100 × V₂
F: V₂ = 400 ÷ 100
A: 4.0 cm³

Q8 (F/H) A gas cylinder holds 5.0 × 10−2 m³ of gas at 1.2 × 107 Pa. What volume would the gas take up at 1.0 × 105 Pa?

Show solution

F: p₁V₁ = p₂V₂
I: 1.2 × 107 × 5.0 × 10−2 = 1.0 × 105 × V₂
F: V₂ = 6.0 × 105 ÷ 1.0 × 105
A: 6.0 m³

Q9 (H) A diver 10 m deep in fresh water breathes out a 3.0 cm³ bubble. Atmospheric pressure is 100 000 Pa. Calculate the bubble’s volume at the surface, to 2 significant figures. (ρ water = 1000 kg/m³, g = 9.8 N/kg)

Show solution

Step 1 – pressure at 10 m: water adds p = h ρ g = 10 × 1000 × 9.8 = 98 000 Pa
total p₁ = 100 000 + 98 000 = 198 000 Pa
Step 2 – volume at surface
F: p₁V₁ = p₂V₂
I: 198 000 × 3.0 = 100 000 × V₂
F: V₂ = 594 000 ÷ 100 000 = 5.94 cm³
A: 5.9 cm³ (2 s.f.)

Q10 (H) 0.75 litres of air at 101 kPa is slowly compressed to 0.32 litres at constant temperature. Calculate the new pressure, to 2 significant figures.

Show solution

F: p₁V₁ = p₂V₂
I: 101 × 0.75 = p₂ × 0.32
F: p₂ = 75.75 ÷ 0.32 = 236.7 kPa
A: 240 kPa (2 s.f.)