The Physics Question Bank

Bond Energy Calculations

โœ๏ธ Paper first! Work out every question on paper before you open the answer. Write down every step โ€“ the equation, the numbers with units, the rearranging and the answer with its unit. In the exam, if your final answer is wrong you can still get marks for correct working, but only if the examiner can see it.

Count the bonds in displayed formulas, then work out the energy taken in, the energy given out and the overall energy change. Every reaction uses the given bond energies below.

The rules
  1. Breaking bonds takes in energy. Making bonds gives out energy. All the bonds in the reactants break, and all the bonds in the products form.
  2. Count every bond in the displayed formula. CH4 has 4 Cโ€“H bonds. H2O has 2 Oโ€“H bonds.
  3. Multiply by the big number in front of the formula. 2O2 means 2 O=O bonds to break.
  4. Double and triple bonds have their own values. C=O is 805 kJ/mol, not the Cโ€“O value of 358 kJ/mol.
  5. Energy change = bonds broken โˆ’ bonds made. Always this way round.
  6. Negative means exothermic: more energy is given out making bonds than is taken in breaking them. Positive means endothermic.
Bond energy table

These are given values in kJ/mol, as you would see them in an exam question. Different data books give slightly different values, so always use the ones in the question.

Topic
Level
0correct 0attempted 0streak

Worked solution

    Bond energies are given values in kJ/mol: Hโ€“H 436, Clโ€“Cl 243, Hโ€“Cl 432, O=O 498, Oโ€“H 464, Cโ€“H 413, C=O 805, Cโ€“C 347, C=C 612, Nโ‰กN 945, Nโ€“H 391, Hโ€“Br 366, Brโ€“Br 193, Cโ€“O 358, Cโ€“Cl 346, Cโ€“Br 276. Calculating energy changes from bond energies is Higher tier content.

    Answers within 1% are marked correct. For an overall energy change, include the sign: type โˆ’185 or +93.

    ๐Ÿ›’ Want it all printable? Revision booklets, PowerPoints and workbooks are in the Physics Question Bank store on Payhip.